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Merck
CN

364673

Ethylmagnesium bromide solution

1.0 M in THF

Synonym(s):

EtMgBr solution

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About This Item

Linear Formula:
CH3CH2MgBr
CAS Number:
Molecular Weight:
133.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587203
Concentration:
1.0 M in THF
Form:
liquid
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form

liquid

Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal of

concentration

1.0 M in THF

density

1.010 g/mL at 25 °C

SMILES string

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

Application

Ethylmagnesium bromide solution can be used in Grignard reaction and to synthesize other Grignard reagents.

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


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signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

23.0 °F - closed cup

flash_point_c

-5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1



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