364673
Ethylmagnesium bromide solution
1.0 M in THF
Synonym(s):
EtMgBr solution
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About This Item
Linear Formula:
CH3CH2MgBr
CAS Number:
Molecular Weight:
133.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587203
Concentration:
1.0 M in THF
Form:
liquid
form
liquid
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF
density
1.010 g/mL at 25 °C
SMILES string
CC[Mg]Br
InChI
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key
TWTWFMUQSOFTRN-UHFFFAOYSA-M
Application
Ethylmagnesium bromide solution can be used in Grignard reaction and to synthesize other Grignard reagents.
Packaging
Other Notes
Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
23.0 °F - closed cup
flash_point_c
-5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
Regulatory Information
危险化学品
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Replacement of the lactone moiety on podophyllotoxin and steganacin analogues with a 1, 5-disubstituted 1, 2, 3-triazole via ruthenium-catalyzed click chemistry.
Imperio D
Bioorganic & Medicinal Chemistry, 15(21), 6748-6757 (2007)
An improved synthesis of (+)-3, 4-O-isopropylidene butyne.
Jiang B
Synthetic Communications, 25(22), 3641-3645 (1995)
D R Hwang et al.
Nuclear medicine and biology, 27(6), 533-539 (2000-11-01)
Imaging neuroreceptors with radiolabeled agonists might provide valuable information on the in vivo agonist affinity states of receptors of interest. We report here the radiosynthesis, biodistribution in rodents, and imaging studies in baboons of [(11)C]-labeled (-)-N-propyl-norapomorphine [(-)-NPA]. (-)-[(11)C]NPA was prepared
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 364673-4X25ML | 04065268447437 |
| 364673-100ML | 04061831825503 |
| 364673-800ML | 04061831825510 |