376353
Z-α-Phosphonoglycine trimethyl ester
97%
Synonym(s):
(±)-Z-α-Phosphonoglycine trimethyl ester, (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate, (±)-Trimethyl Z-α-phosphonoglycinate
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About This Item
Linear Formula:
(CH3O)2P(O)CH(NHCO2CH2C6H5)CO2CH3
CAS Number:
Molecular Weight:
331.26
UNSPSC Code:
12352209
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5764460
InChI
1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16)
SMILES string
COC(=O)C(NC(=O)OCc1ccccc1)P(=O)(OC)OC
InChI key
GSYSFVSGPABNNL-UHFFFAOYSA-N
assay
97%
reaction suitability
reaction type: solution phase peptide synthesis
mp
77-80 °C (lit.)
application(s)
peptide synthesis
Quality Level
Application
Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids.
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