394262
十八烷基氯化镁 溶液
0.5 M in THF
别名:
Chlorooctadecylmagnesium, Octadecane, magnesium complex
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关于此项目
线性分子式:
CH3(CH2)17MgCl
化学文摘社编号:
分子量:
313.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
bp
67 °C
density
0.906 g/mL at 25 °C
SMILES string
CCCCCCCCCCCCCCCCCC[Mg]Cl
InChI
1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
InChI key
ONJPXWZQVLKGIU-UHFFFAOYSA-M
General description
Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.
Application
Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
supp_hazards
存储类别
3 - Flammable liquids
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system