407739
L-tert-Leucinol
98%, for peptide synthesis
Synonym(s):
(S)-2-Amino-3,3-dimethyl-1-butanol
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About This Item
Linear Formula:
(CH3)3CCH(NH2)CH2OH
CAS Number:
Molecular Weight:
117.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
Beilstein/REAXYS Number:
3600321
Product Name
L-tert-Leucinol, 98%
Quality Level
assay
98%
optical activity
[α]26/D +37°, c = 1.5 in ethanol
reaction suitability
reaction type: solution phase peptide synthesis
mp
30-34 °C (lit.)
density
0.9 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
SMILES string
CC(C)(C)[C@H](N)CO
InChI
1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1
InChI key
JBULSURVMXPBNA-RXMQYKEDSA-N
Application
Useful amino acid employed in various asymmetric reactions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.
Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron, 60, 4459-4473 (2004)
Tetrahedron Letters, 45, 5649-5649 (2004)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 407739-5G | 04061838119704 |
| 407739-1G | 04061831988338 |