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Merck
CN

424684

Phenethylmagnesium chloride solution

1.0 M in THF

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About This Item

Linear Formula:
C6H5CH2CH2MgCl
CAS Number:
90878-19-6
Molecular Weight:
164.92
NACRES:
NA.22
PubChem Substance ID:
24866584
UNSPSC Code:
12352103
MDL number:
MFCD00192387

Key Documents

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Product Name

Phenethylmagnesium chloride solution, 1.0 M in THF

InChI

1S/C8H9.ClH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1

SMILES string

Cl[Mg]CCc1ccccc1

InChI key

AZORNQXQALOFHH-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

bp

65 °C

density

0.954 g/mL at 25 °C

functional group

phenyl

Quality Level

200

Related Categories

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Faceshields, Gloves, Goggles

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ9255
SHBP8337
SHBP4231
SHBL8586
SHBL6675

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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method

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