444413
N-(tert-Butoxycarbonyl)-L-valinol
96%
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About This Item
Linear Formula:
(CH3)2CHCH[NHCO2C(CH3)3]CH2OH
CAS Number:
Molecular Weight:
203.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
InChI
1S/C10H21NO3/c1-7(2)8(6-12)11-9(13)14-10(3,4)5/h7-8,12H,6H2,1-5H3,(H,11,13)/t8-/m1/s1
SMILES string
CC(C)[C@@H](CO)NC(=O)OC(C)(C)C
InChI key
OOQRRYDVICNJGC-MRVPVSSYSA-N
assay
96%
form
liquid
optical activity
[α]23/D −23°, c = 1 in chloroform
reaction suitability
reaction type: solution phase peptide synthesis
refractive index
n20/D 1.449 (lit.)
bp
208 °C (lit.)
density
0.995 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
Quality Level
Application
Starting material for the synthesis of enantiopure homo-β-amino acids. Used in the efficient synthesis of enantiopure tetrahydroisoquinolines. Intermediate in the one-pot conversion of amino acid carbamates to N-derivatized 2-oxazolidinones.
Storage Class
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Huwe, C.M. Blechert, S.
Tetrahedron Letters, 35, 9533-9533 (1994)
Tietze, L.F. Burkhardt, O.
Synthesis, 1331-1331 (1994)
R. Caputo et al.
Tetrahedron Letters, 36, 167-167 (1995)
Caputo, R. et al.
Tetrahedron, 51, 12337-12337 (1995)
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