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About This Item
Linear Formula:
CH3SO2Cl
CAS Number:
Molecular Weight:
114.55
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-706-1
Beilstein/REAXYS Number:
506297
MDL number:
Assay:
≥99.7%
Quality Level
assay
≥99.7%
refractive index
n20/D 1.452 (lit.)
bp
60 °C/21 mmHg (lit.)
density
1.48 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CS(Cl)(=O)=O
InChI
1S/CH3ClO2S/c1-5(2,3)4/h1H3
InChI key
QARBMVPHQWIHKH-UHFFFAOYSA-N
Application
Methanesulfonyl chloride can be used for the mesylation of primary alcohols to synthesize the corresponding methanesulfonates. It may also be used for the conversion of amines to the corresponding sulfonamides.
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
监管及禁止进口产品
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Methanesulfonyl Chloride.
Vaillancourt V
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Water-solvent method for tosylation and mesylation of primary alcohols promoted by KOH and catalytic amines.
Morita J I
Green Chemistry, 7(10), 711-715 (2005)
Shengzhuang Tang et al.
The Journal of organic chemistry, 85(5), 2945-2955 (2020-02-06)
Despite its importance in the design of photocaged molecules, less attention is focused on linker chemistry than the cage itself. Here, we describe unique uncaging properties displayed by two coumarin-caged thymidine compounds, each conjugated with (2) or without (1) an
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 471259-1L | 04061832359687 |
| 471259-5ML | 04061837790447 |
| 471259-100ML | 04061837790423 |
| 471259-500ML | 04061832359694 |
| 471259-2L | 04061838135643 |

