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Merck
CN

473464

tert-Butylchlorodimethylsilane solution

50 wt. % in toluene

Synonym(s):

tert-Butyldimethylchlorosilane, tert-Butyldimethylsilyl chloride, TBDMSCl solution

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About This Item

Linear Formula:
(CH3)3CSi(CH3)2Cl
CAS Number:
18162-48-6
Molecular Weight:
150.72
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24870907
MDL number:
MFCD00000501
Beilstein/REAXYS Number:
505999

Key Documents

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Product Name

tert-Butylchlorodimethylsilane solution, 50 wt. % in toluene

InChI

1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3

SMILES string

CC(C)(C)[Si](C)(C)Cl

InChI key

BCNZYOJHNLTNEZ-UHFFFAOYSA-N

concentration

50 wt. % in toluene

refractive index

n20/D 1.46

bp

113 °C

density

0.87 g/mL at 20 °C (lit.)
0.866 g/mL at 25 °C

Quality Level

200

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Related Categories

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

44.6 °F - closed cup

flash_point_c

7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB1111
MKCS1450
MKCS3384
MKCK0244
SHBL1010

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Akshanth R Polepally et al.
Journal of clinical pharmacology, 55(10), 1101-1108 (2015-04-24)
A classic 2-period crossover bioavailability study was conducted to evaluate the relative and absolute bioavailability of immediate-release (IR) and extended-release (XR) lamotrigine formulations under steady-state conditions in elderly patients with epilepsy. On treatment days, each subject's morning dose (IR or
Hiroaki Wakimoto et al.
Clinical cancer research : an official journal of the American Association for Cancer Research, 20(11), 2898-2909 (2014-04-10)
Isocitrate dehydrogenase (IDH) gene mutations occur in low-grade and high-grade gliomas. We sought to identify the genetic basis of malignant phenotype heterogeneity in IDH-mutant gliomas. We prospectively implanted tumor specimens from 20 consecutive IDH1-mutant glioma resections into mouse brains and
Some observations on the t-butyldimethylchlorosilane derivatization reaction.
K Bricknell et al.
Biochemical medicine, 23(1), 119-121 (1980-02-01)
P Huttenloch et al.
Environmental science & technology, 35(21), 4260-4264 (2001-11-23)
The efficacy of the surface modification of natural diatomite and zeolite material by chlorosilanes is demonstrated. Chlorosilanes used were trimethylchlorosilane (TMSCI), tert-butyldimethylchlorosilane (TBDMSCI), dimethyloctadecylchlorosilane (DMODSCI), and diphenyldichlorosilane (DPDSCI) possessing different headgroups and chemical properties. Silanol groups of the diatomite and
C Tellis et al.
Journal of biochemistry, 119(4), 823-827 (1996-04-01)
1-O-Hexadecyl-2-acetyl-sn-glycerol, the immediate precursor of platelet- activating factor (PAF) in its de novo formation, was detected in the protozoon Tetrahymena pyriformis. It was purified from the total lipid extract by TLC, after successive developments in two different solvent systems. Characterization
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