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Merck
CN

516988

Cesium hydroxide monohydrate

99.95% trace metals basis

Synonym(s):

2-Aminoethyl 2-methylacrylate hydrochloride, 2-Aminoethyl methacrylate hydrochloride, Methacrylic acid, 2-aminoethyl ester, hydrochloride

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About This Item

Empirical Formula (Hill Notation):
HCsO · H2O
CAS Number:
35103-79-8
Molecular Weight:
167.93
NACRES:
NA.23
PubChem Substance ID:
24873911
UNSPSC Code:
12352302
EC Number:
244-344-1
MDL number:
MFCD00010964
Assay:
99.95% trace metals basis
Form:
powder

Key Documents

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InChI key

HUCVOHYBFXVBRW-UHFFFAOYSA-M

InChI

1S/Cs.H2O/h;1H2/q+1;/p-1

SMILES string

[Cs+].[O-][H].[H]O[H]

assay

99.95% trace metals basis

form

powder

impurities

≤550.0 ppm Trace Metal Analysis

mp

272 °C (lit.)

density

3.68 g/mL at 25 °C (lit.)

Quality Level

100

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General description

Cesium hydroxidemonohydrate is commonly used as a catalyst in many organic transformations andas an initiator in polymerization reactions.

Application

Cesium hydroxide monohydrate can be used as a catalyst in the synthesis of:
  • O-allenes and N-allenes via isomerization of terminal alkynes. This method allows the efficient synthesis of allenes in high yields under mild conditions with wide functional group tolerance.
  • Unsymmetrical bis-allyl ethers consist of an E-allylic unit and a terminal allylic unit via dimerization of Baylis-Hillman adducts.
Cesium hydroxide monohydrate can also be used as an initiator for the heterogeneous ring-opening polymerization of monosubstituted oxiranes.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

非剧毒-急性毒性1
危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKDB0986
0000473228
0000473228
0000471084
0000471084

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A S Malkani et al.
Science advances, 6(45) (2020-11-08)
Electrolyte cations affect the activity of surface-mediated electrocatalytic reactions; however, understanding the modes of interaction between cations and reaction intermediates remains lacking. We show that larger alkali metal cations (excluding the thickness of the hydration shell) promote the electrochemical CO
David Johannes Scholz et al.
Magma (New York, N.Y.), 28(6), 591-598 (2015-10-10)
(13)C metabolic MRI using hyperpolarized (13)C-bicarbonate enables preclinical detection of pH. To improve signal-to-noise ratio, experimental procedures were refined, and the influence of pH, buffer capacity, temperature, and field strength were investigated. Bicarbonate preparation was investigated. Bicarbonate was prepared and
Andrea Šlampová et al.
Analytica chimica acta, 887, 92-100 (2015-09-01)
Electrolysis is omnipresent in all electrochemical processes including electromembrane extraction (EME). The effects of electrolysis on quantitative aspects of EME were comprehensively evaluated for a set of acidic (substituted phenols) and basic (basic drugs) analytes. EMEs were carried out across

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