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Merck
CN

520330

Fluoro-N,N,N′,N′-tetramethylformamidinium hexafluorophosphate

97%

Synonym(s):

TFFH

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About This Item

Linear Formula:
[FC[=N(CH3)2]N(CH3)2]PF6
CAS Number:
164298-23-1
Molecular Weight:
264.12
NACRES:
NA.22
PubChem Substance ID:
24874106
UNSPSC Code:
12352107
MDL number:
MFCD02684443

Key Documents

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Product Name

Fluoro-N,N,N′,N′-tetramethylformamidinium hexafluorophosphate, 97%

InChI

1S/C5H12FN2.F6P/c1-7(2)5(6)8(3)4;1-7(2,3,4,5)6/h1-4H3;/q+1;-1

SMILES string

F[P-](F)(F)(F)(F)F.CN(C)\C(F)=[N+](/C)C

InChI key

ZAVXOOLKAGPJPI-UHFFFAOYSA-N

assay

97%

reaction suitability

reaction type: Coupling Reactions

mp

104-109 °C (lit.)

application(s)

peptide synthesis

functional group

amine
fluoro

Quality Level

100

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Related Categories

Application

Reagent for synthesis of:
Cationic antimicrobial β-2,2-amino acid derivatives
Philanthotoxin analogues for inhibition of the ionotropic glutamate receptor
Small β-peptidomimetics for antimicrobials
Amine prodrugs of selective neuronal nitric oxide synthase inhibitors

Reagent for:
Selective cyclohexyl-derived imidazopyrazine insulin-like growth factor 1 receptor inhibitors
Hydrazone ligation to assemble multifunctional viral nanoparticles

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV0820
MKCB8876
MKBQ3402V
MKBL2829V
MKBF0856V

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Anita K Kovács et al.
Frontiers in chemistry, 6, 120-120 (2018-05-05)
A general strategy for the synthesis of N-peptide-6-amino-D-luciferin conjugates has been developed. The applicability of the strategy was demonstrated with the preparation of a known substrate, N-Z-Asp-Glu-Val-Asp-6-amino-D-luciferin (N-Z-DEVD-aLuc). N-Z-DEVD-aLuc was obtained via a hybrid liquid/solid phase synthesis method, in which

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