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531480

Fmoc-Ala-OH

Name: Fmoc-Ala-OH
Brand: ALDRICH

95%, for peptide synthesis

Synonym(s):

N-(9-Fluorenylmethoxycarbonyl)-L-alanine, Fmoc-L-alanine

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About This Item

Empirical Formula (Hill Notation):

C₁₈H₁₇NO₄

CAS Number:

35661-39-3

Molecular Weight:

311.33

NACRES:

NA.26

PubChem Substance ID:

24877820

UNSPSC Code:

12352209

EC Number:

252-660-6

MDL number:

MFCD00037139

Beilstein/REAXYS Number:

2225975

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Properties

Product Name

Fmoc-Ala-OH, 95%

Quality Level

100

assay

95%

optical activity

[α]20/D −18°, c = 1 in DMF

reaction suitability

reaction type: C-H Activation, reaction type: Fmoc solid-phase peptide synthesis, reagent type: ligand
reaction type: Peptide Synthesis

mp

147-153 °C (lit.)

application(s)

peptide synthesis

functional group

Fmoc, amine, carboxylic acid

storage temp.

2-8°C

SMILES string

C[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O

InChI

1S/C18H17NO4/c1-11(17(20)21)19-18(22)23-10-16-14-8-4-2-6-12(14)13-7-3-5-9-15(13)16/h2-9,11,16H,10H2,1H3,(H,19,22)(H,20,21)/t11-/m0/s1

InChI key

QWXZOFZKSQXPDC-NSHDSACASA-N

Description

General description

Fmoc-Ala-OH also known as Fmoc-L-alanine, is a versatile reagent used in Fmoc solid-phase peptide synthesis.

Application

Fmoc-Ala-OH is commonly used :

as a building block in the preparation of triazolopeptides , and azapeptides
in the synthesis of bis-cationic porphyrin peptides using the standard Fmoc solid-phase synthesis
to transform Mannich-adducts into α-halogenated amides without undergoing aziridination

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Towards sequence selective DNA binding: design, synthesis and DNA binding studies of novel bis-porphyrin peptidic nanostructures

E Biron

Organic & Biomolecular Chemistry, 6, 2507-2515 (2008)

Synthesis and characterization of chemically fueled supramolecular materials driven by carbodiimide-based fuels.

Fabian Schnitter et al.

Nature protocols, 16(8), 3901-3932 (2021-07-02)

Many supramolecular materials in biological systems are driven to a nonequilibrium state by the irreversible consumption of high-energy molecules such as ATP or GTP. As a result, they exhibit unique dynamic properties such as a tunable lifetime, adaptivity or the

? -Halo amides as competent latent enolates: direct catalytic asymmetric Mannich-type reaction

B Sun

Journal of the American Chemical Society, 139, 8295-8301 (2017)

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Global Trade Item Number

SKU	GTIN
531480-100G	04061832558714
531480-1KG	04061832642710
531480-25G	04061832558721
531480-5G	04061832558738