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Merck
CN

662623

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)]

greener alternative

95%, solid

Synonym(s):

Rh2(esp)2

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About This Item

Empirical Formula (Hill Notation):
C32H40O8Rh2
CAS Number:
Molecular Weight:
758.47
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)], 95%

Quality Segment

assay

95%

form

solid

reaction suitability

core: rhodium, reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C

greener alternative category

SMILES string

[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O

InChI

1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;

InChI key

OBMUTUNJWNQIAJ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.
Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionicacid)] has been identified as efficient C-H activation catalyst.

Application

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionicacid)] is used as a catalyst for oxidative C−H amination of urea and guanidinederived substrates to yield corresponding heterocyclic products.


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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