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Merck
CN

669431

Lithium fluoride

greener alternative

Precipitated, 99.995%

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
7789-24-4
Molecular Weight:
25.94
NACRES:
NA.23
PubChem Substance ID:
24885048
UNSPSC Code:
12352302
EC Number:
232-152-0
MDL number:
MFCD00011090
Assay:
99.995%
Form:
powder

Key Documents

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InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

InChI

1S/FH.Li/h1H;/q;+1/p-1

assay

99.995%

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
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impurities

≤55.0 ppm Trace Metal Analysis

mp

845 °C (lit.)

density

2.64 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

greener alternative category

Enabling

Quality Level

100

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General description

Lithium fluoride is an inorganic halide with good ionic conductivity, high refractive index, and high transmittance in the UV region. Owing to its unique properties, it is widely used in the field of optical and electronic devices, X-ray imaging, and dental materials.
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Application

Lithium fluoride(LiF) can be used:
  • To fabricate an insulating layer in AC-driven organic light-emitting diodes(OLEDs). LiF provides excellent capacitance and high stability to the insulating layers in AC devices.
  • As a precursor to synthesize Eu2+/Ce3+ doped barium lithium fluoride phosphors by solvothermal method.
  • To fabricate LiF thin film coating on the lithium anodes to enhance their stability and coulombic efficiency.
  • As an additive to enrich and enhance the performance of solidelectrolyte interface(SEI) in Li metal batteries.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH032

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ9801
MKCX9240
MKCV6343
MKCS3714
MKCR0177

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Alternating current driven organic light emitting diodes using lithium fluoride insulating layers
Shang-Yi Liu, et al.
Scientific Reports, 4, 7559-7559 (2014)
Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes
Lin Chen, et al.
ACS Applied Materials & Interfaces, 10, 26972-26981 (2018)
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium
Mingfu He, et al.
Proceedings of the National Academy of Sciences, 117, 73-79 (2020)
Solvothermal fabrication and luminescent properties of Eu2+/Ce3+ doped barium lithium fluoride
Guoxian ZHU, et al.
Journal of Rare Earths, 30, 985-989 (2012)
X W Meng et al.
The journal of physical chemistry. B, 115(16), 4768-4773 (2011-04-06)
On the basis of molecular dynamics simulations, we investigate water permeation across a single-walled carbon nanotube (SWCNT) under the influence of four symmetrical half-rings, each having six LiF dipolar molecules. The flux remains almost fixed as the separation, R, between
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