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687952

(Cyclohexylmethyl)magnesium bromide solution

Synonym(s):

Cyclohexylmethylmagnesium bromide

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About This Item

Empirical Formula (Hill Notation):
C7H13BrMg
CAS Number:
35166-78-0
Molecular Weight:
201.39
NACRES:
NA.22
PubChem Substance ID:
329760828
UNSPSC Code:
12352103
MDL number:
MFCD02260210
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form

liquid

Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

density

0.966 g/mL at 25 °C

SMILES string

Br[Mg]CC1CCCCC1

InChI

1S/C7H13.BrH.Mg/c1-7-5-3-2-4-6-7;;/h7H,1-6H2;1H;/q;;+1/p-1

InChI key

ZBCIOGFGZRNNEC-UHFFFAOYSA-M

Application

Reactant involved in:
  • Isomerization polymerization of alkenylcyclohexanes
  • Intramolecular rearrangements of vinylidenecyclopropanes
  • Cycloisomerization of cyclic and acyclic enynes

Additionally reactant involved in synthesis of biologically active molecules including:
  • Dipeptidyl boronic acid proteasome inhibitors
  • Substituted 1,3-dihydroindole-2-ones with antitumor effects
  • Sulfur-free transition state nucleoside analog inhibitors of methylthioadenosine nucleosidase and phosphorylase

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

Flash Point (°F)

-4.0 °F

Flash Point (°C)

-20 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

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