703559
Lanthanum(III) chloride bis(lithium chloride) complex solution
0.6 M in THF
Synonym(s):
Lanthanum trichloride lithium chloride complex
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About This Item
SMILES string
[Li]Cl.[Li]Cl.Cl[La](Cl)Cl
InChI
1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
InChI key
YSKOYVQYUJUXCN-UHFFFAOYSA-I
form
liquid
concentration
0.6 M in THF, 16 % (w/w)
density
1.05 g/mL at 25 °C
Quality Level
reaction suitability
reagent type: catalyst
core: lanthanum
reaction type: Grignard Reaction
Related Categories
Application
- Mediates Grignard additions
- Reagent for metal exchange reactions
- Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
62.6 °F
flash_point_c
17 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Articles
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
Grignard reagent's 1,2-addition to ketones is powerful but selective issues often arise from competitive alpha-deprotonation.
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