725455
Rhodium(II) triphenylacetate dimer
solid, as complex with dichloromethane
Synonym(s):
Rh2(TPA)4, Rh2(triphenylacetate)4, Rhodiumtriphenylacetate, Tetrakis(triphenylacetato)dirhodium(II)
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About This Item
Product Name
Rhodium(II) triphenylacetate dimer, as complex with dichloromethane
InChI key
SRAMLXDHXNCYQM-UHFFFAOYSA-J
InChI
1S/4C20H16O2.CH2Cl2.2Rh/c4*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1-3;;/h4*1-15H,(H,21,22);1H2;;/q;;;;;2*+2/p-4
SMILES string
ClCCl.O=C(O[Rh](OC(=O)C(c1ccccc1)(c2ccccc2)c3ccccc3)[Rh](OC(=O)C(c4ccccc4)(c5ccccc5)c6ccccc6)OC(=O)C(c7ccccc7)(c8ccccc8)c9ccccc9)C(c%10ccccc%10)(c%11ccccc%11)c%12ccccc%12
form
solid
reaction suitability
core: rhodium, reagent type: catalyst
reaction type: C-H Activation
mp
260-263 °C
Quality Level
Application
- Amination of allene carbamates
- Allene aziridination to stereoselectively prepare cyclic cabamates
- C-H bond nitrene insertion
- Enantioselective cyclopropanation
- Preparation of cyclic oxonium ylides
signalword
Warning
hcodes
Hazard Classifications
Carc. 2
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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