762261
二氯[1,3-双（2,4,6-三甲基苯基）-2-咪唑烷亚基] [[5-[（二甲基氨基）磺酰基] -2-（1-甲基乙氧基-O）苯基]亚甲基 C]钌（II）
solid
别名:
詹氏催化剂-1B
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关于此项目
经验公式（希尔记法）:
C33H43Cl2N3O3RuS
化学文摘社编号:
分子量:
733.75
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
二氯[1,3-双（2,4,6-三甲基苯基）-2-咪唑烷亚基] [[5-[（二甲基氨基）磺酰基] -2-（1-甲基乙氧基-O）苯基]亚甲基 C]钌（II）,
form
solid
Quality Segment
reaction suitability
core: ruthenium, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
SMILES string
[Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[S](=O)(=O)N(C)C)OC(C)C.[Cl-].[Cl-]
InChI
1S/C21H26N2.C12H17NO3S.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-9(2)16-12-7-6-11(8-10(12)3)17(14,15)13(4)5;;;/h9-12H,7-8H2,1-6H3;3,6-9H,1-2,4-5H3;2*1H;/q;;;;+2/p-2
InChI key
OXLURKCRXVAJQS-UHFFFAOYSA-L
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is utilized to catalyze the ring-closing metathesis of a sterically hindered diene intermediate to form a spiro-ring system, showing superior reactivity compared to standard Grubbs catalysts. Click here for more information.
Application
詹氏催化剂-1B（Hoveyda-Grubbs型催化剂）可用于：
- 制备复合烯烃复分解反应催化剂，通过在分子筛上固定而获得更高的催化活性
- 作为合成发散型树形分子的催化剂
- 关环复分解 (RCM) 反应。
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable