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Merck
CN

763756

Yttrium-doped ceria

greener alternative

nanopowder, yttria 20 mol %, <50 nm particle size (TEM), 99.9% trace metals basis

别名:

20YDC, Cerium(IV) oxide-yttria doped, YDC-20, YDC20, Cerium yttrium oxide, YDC, Yttria doped ceria, Yttrium doped ceria

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关于此项目

经验公式(希尔记法):
CeO2/Y2O3
化学文摘社编号:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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产品名称

氧化钇掺杂的氧化铈(IV), nanopowder, yttria 20 mol %, <50 nm particle size (TEM), 99.9% trace metals basis

Quality Segment

assay

99.9% trace metals basis

form

nanopowder

composition

yttria, 20 mol %

reaction suitability

core: cerium

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

Greener Alternative Product

particle size

<50 nm (TEM)

application(s)

catalysts
glass & ceramic
hydrogen and fuel cell

greener alternative category

SMILES string

O=[Ce]=O.O=[Y]O[Y]=O

InChI

1S/Ce.5O.2Y

InChI key

XVLUKJGVKWVXMP-UHFFFAOYSA-N

General description

8mol% Yttria doped ceria may be prepared by carbonate coprecipitation technique. Yttria doped ceria exhibits high ionic conductivity, low activation energy and small grain boundary resistance. The effect of microstructure on the electrolytic properties was investigated in detail.
Cerium(IV) oxide-yttria doped (YDC-20) is an electrolytic material that is used as an alternative to zirconia-based electrolytes. Its properties include high ionic conductivity (0.01 S cm−1), electronic conductivity (3 S cm−1), enhanced electrode reactions, and high oxygen surface exchange coefficient.
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Application

YDC-20 can be used as an electrolyte in the fabrication of solid oxide fuel cells (SOFCs). A thin film of YDC-20 (~17.5 nm) effectively reduces the cathode/interfacial energy by 0.1 eV and increases the exchange current density by a factor of 4. It can be operated with a temperature range of 300° - 500°C.
They are promising ceramic electrolytes for solid oxide fuel cells operating at low temperatures of 500-700°C (IT-SOFC). Doped ceria interlayers in between bulk yttria-stabilized zirconia electrolyte further enhance the performance of SOFCs.


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存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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