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772836

Isopropenylmagnesium bromide solution

1.0 M in 2-methyltetrahydrofuran

Sustainability features

Synonym(s):

1-Methylvinylmagnesium bromide, 1-Propen-2-ylmagnesium bromide, 2-Propen-2-ylmagnesium bromide, Bromo prop-1-en-2-yl magnesium, Bromo(isopropenylmagnesium), Isopropenylmagnesium bromide

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About This Item

Linear Formula:
CH2=C(CH3)MgBr
CAS Number:
13291-18-4
Molecular Weight:
145.28
PubChem Substance ID:
329766609
UNSPSC Code:
12352103
NACRES:
NA.22
EC Index Number:
603-688-6
Beilstein/REAXYS Number:
3587297
MDL number:
MFCD00192240
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form

solution

Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

sustainability

Sustainability features

concentration

1.0 M in 2-methyltetrahydrofuran

density

0.970 g/mL

greener alternative category

storage temp.

2-8°C

SMILES string

CC(=C)[Mg]Br

InChI

1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

LFTYALBVGVNGLI-UHFFFAOYSA-M

General description

This product aligns with one or more of the 12 Principles of Green ChemistryThis product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Signal Word

Danger

supp_hazards

EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Flash Point (°F)

57.2 °F - closed cup

Flash Point (°C)

14 °C - closed cup

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react. 1

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