775258
Grubbs Catalyst® M202
Umicore, powder
别名:
Grubbs Catalyst® M2, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)
选择规格
关于此项目
产品名称
Grubbs Catalyst® M202, Umicore
Quality Segment
product line
Grubbs Catalyst® M200 Series
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
manufacturer/tradename
Umicore Grubbs Catalyst® M200 Series
mp
159 (d)-162 °C
storage temp.
2-8°C
SMILES string
[Ru+2](=C7N(CCN7c9c(cc(cc9C)C)C)c8c(cc(cc8C)C)C)=C4c5c(cccc5)C(=C4)c6ccccc6.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1.[Cl-].[Cl-]
InChI
1S/C21H26N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2
InChI key
MCNUJWCJGIGFBS-UHFFFAOYSA-L
Application
- Oxa-Cages Synthesis: Grubbs Catalyst® M202 is utilized in a synthetic approach for creating diverse oxa-cages via olefin metathesis, enhancing the scope of organic synthesis with high selectivity and efficiency in forming complex cyclic structures (Kotha et al., 2024).
- Phosphoproline Analogues: This article details the stereocontrolled synthesis of complex bicyclic systems, a type of chemical transformation where Grubbs Catalyst® M202 could potentially be applied for enhancing reaction pathways and outcomes in pharmaceutical synthesis (Hernández-Benítez et al., 2024).
Legal Information
Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable