Isopropylmagnesium bromide solution

Name: Isopropylmagnesium bromide solution
Brand: ALDRICH

0.75 M in THF

Synonym(s):

1-Methylethylmagnesium bromide, 2-Propylmagnesium bromide, iso-Propylmagnesium bromide, Bromoisopropylmagnesium

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Linear Formula:

(CH₃)₂MgBr

CAS Number:

Molecular Weight:

147.30

NACRES:

NA.22

PubChem Substance ID:

UNSPSC Code:

12352103

MDL number:

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Properties

solution

reaction type: Grignard Reaction

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0.75 M in THF

0.982 g/mL at 25 °C

2-8°C

CC(C)[Mg]Br

1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

UCJIVFREPMUZDC-UHFFFAOYSA-M

Description

Preparation of isopropylmagnesium bromide solutions: In this study, various concentrations of isopropylmagnesium bromide solutions were prepared, detailing their stability and reactivity for use in palladium-catalyzed cross-coupling reactions and other synthetic applications (Vulović et al., 2017).
Reductive coupling of amides: This research discusses the reductive functionalization of tertiary amides using isopropylmagnesium bromide, providing a novel method for amine synthesis, which is crucial for pharmaceutical chemistry (Xie and Dixon, 2017).
Synthesis of 1, 2, 3-triazoles: The study explores the use of isopropylmagnesium bromide in the synthesis of 1, 2, 3-triazoles through Grignard reactions, highlighting its role in protecting azides during the reaction process (Namioka et al., 2023).
Disposable cartridge concept for Grignard reagents: This paper introduces a novel disposable cartridge for the on-demand synthesis of Grignard reagents, including isopropylmagnesium bromide, enhancing the safety and scalability of Grignard reactions (Berton et al., 2020).