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798215

L-Fmoc-4-fluorophenylalanine

Name: <SC>L</SC>-Fmoc-4-fluorophenylalanine
Brand: ALDRICH

Synonym(s):

Fmoc-Phe(4-F)-OH, N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-4-fluoro-L-phenylalanine, Fmoc-4-fluoro-L-phenylalanine

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About This Item

Empirical Formula (Hill Notation):

C₂₄H₂₀FNO₄

CAS Number:

169243-86-1

Molecular Weight:

405.42

UNSPSC Code:

12352209

NACRES:

NA.22

PubChem Substance ID:

329768632

MDL number:

MFCD00191197

Beilstein/REAXYS Number:

8287377

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Properties

form

solid

Quality Segment

100

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

color

white

application(s)

peptide synthesis

functional group

Fmoc

storage temp.

2-8°C

SMILES string

OC(=O)[C@H](Cc1ccc(F)cc1)NC(=O)OCC2c3ccccc3-c4ccccc24

InChI

1S/C24H20FNO4/c25-16-11-9-15(10-12-16)13-22(23(27)28)26-24(29)30-14-21-19-7-3-1-5-17(19)18-6-2-4-8-20(18)21/h1-12,21-22H,13-14H2,(H,26,29)(H,27,28)/t22-/m0/s1

InChI key

IXUMACXMEZBPJG-QFIPXVFZSA-N

Description

Application

Phenylalanine derivative was introduced in collaboration with Yu and coworkers in reflection to a methodology reported in C-H Activation.

Other Notes

Ligand-Controlled C(sp³)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino

Acids

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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