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905321

Rh2(R-TCPTAD)4

powder, crystals or chunks

Synonym(s):

Davies dirhodium catalyst

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About This Item

Empirical Formula (Hill Notation):
C80H64Cl16N4O16Rh2
CAS Number:
2223621-11-0
Molecular Weight:
2110.44
MDL number:
MFCD06407745
NACRES:
NA.22
UNSPSC Code:
12352101
Form:
powder, crystals or chunks
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Product Name

Rh2(R-TCPTAD)4,

form

powder, crystals or chunks

Application

This dirhodium catalyst developed by the Davies lab can form C-C bonds at the most accessible tertiary C-H position with control of both regioselectivity and absolute configuration.

Other Notes

Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Kuangbiao Liao et al.
Nature, 551(7682), 609-613 (2017-11-21)
The synthesis of complex organic compounds usually relies on controlling the reactions of the functional groups. In recent years, it has become possible to carry out reactions directly on the C-H bonds, previously considered to be unreactive. One of the