918105
(MeBPI)2Ni
≥95%, crystals
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About This Item
Empirical Formula (Hill Notation):
C40H32N10Ni
CAS Number:
Molecular Weight:
711.44
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
Product Name
(MeBPI)2Ni, ≥95%
InChI key
UEBWUPHCLCWDLU-UHFFFAOYSA-N
SMILES string
[Ni+2].[N-]5\C(=N\c8nccc(c8)C)\c6c(cccc6)\C\5=N/c7nccc(c7)C.[N-]1\C(=N\c4nccc(c4)C)\c2c(cccc2)\C\1=N/c3nccc(c3)C
assay
≥95%
form
crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Quality Level
Related Categories
Application
(MeBPI)2Ni is a redox-active shuttle developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with (MeBPI)Ni-OAc (919365), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts
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