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Merck
CN

918105

(MeBPI)2Ni

≥95%, crystals

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关于此项目

经验公式（希尔记法）:
C40H32N10Ni
化学文摘社编号:
78065-33-5
分子量:
711.44
MDL number:
MFCD33021718
UNSPSC Code:
12352103
NACRES:
NA.22

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产品名称

(MeBPI)2Ni, ≥95%

InChI key

UEBWUPHCLCWDLU-UHFFFAOYSA-N

SMILES string

[Ni+2].[N-]5\C(=N\c8nccc(c8)C)\c6c(cccc6)\C\5=N/c7nccc(c7)C.[N-]1\C(=N\c4nccc(c4)C)\c2c(cccc2)\C\1=N/c3nccc(c3)C

assay

≥95%

form

crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Quality Level

100

相关类别

Application

(MeBPI)2Ni is a redox-active shuttle developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with (MeBPI)Ni-OAc (919365), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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