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Merck
CN

925454

AdCyBrettPhos Pd G6 Br

powder

Synonym(s):

Adamantan-1-yl(cyclohexyl)(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane

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About This Item

Empirical Formula (Hill Notation):
C46H61BrF3O2PPd
Molecular Weight:
920.27
UNSPSC Code:
41116105
NACRES:
NA.22

Key Documents

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Product Name

AdCyBrettPhos Pd G6 Br,

SMILES string

Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C(C(OC)=CC=C2OC)=C2C(C(C(C)C)=CC(C(C)C)=C3)=C3C(C)C)(C4CCCCC4)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Quality Level

100

Related Categories

Application

AdCyBrettPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

Storage Class

11 - Combustible Solids

wgk

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR3377

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Articles

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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