926124
(S,S)-Ts-DENEB™
powder
Synonym(s):
stereoisomer of Chloro[4-methyl-N-[(1S,2S)-2-[(R)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium
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About This Item
Empirical Formula (Hill Notation):
C31H33ClN2O3RuS
CAS Number:
Molecular Weight:
650.19
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352116
Product Name
(S,S)-Ts-DENEB™,
form
powder
Quality Level
reaction suitability
reagent type: ligand
functional group
phosphine
Application
(S,S)-Ts-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.
Legal Information
Product of Takasago.
For research and development purposes only. PCT/JP2011/064490
For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 926124-1G | 04065267899701 |
| 926124-5G | 04065267899725 |
| 926124-250MG | 04065267899718 |