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Merck
CN

926124

(S,S)-Ts-DENEB

powder

别名:

stereoisomer of Chloro[4-methyl-N-[(1S,2S)-2-[(R)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium

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关于此项目

经验公式(希尔记法):
C31H33ClN2O3RuS
化学文摘社编号:
分子量:
650.19
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352116
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产品名称

(S,S)-Ts-DENEB,

form

powder

Quality Level

reaction suitability

reagent type: ligand

functional group

phosphine

Application

(S,S)-Ts-DENEB is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.

Legal Information

Product of Takasago.

For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high



全球贸易项目编号

货号GTIN
926124-1G04065267899701
926124-5G04065267899725
926124-250MG04065267899718