T7394
N,N,N′,N′-Tetramethyl-p-phenylenediamine
99%, powder
Synonym(s):
TMPD, TMPDA, TMPPD, Wurster’s reagent
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About This Item
Linear Formula:
C6H4[N(CH3)2]2
CAS Number:
Molecular Weight:
164.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-831-6
Beilstein/REAXYS Number:
1564025
MDL number:
Assay:
99%
Form:
flakes, powder
Quality Level
assay
99%
form
flakes, powder
color
off-white to brown
bp
260 °C (lit.)
mp
49-51 °C (lit.)
SMILES string
CN(C)c1ccc(cc1)N(C)C
InChI
1S/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3
InChI key
CJAOGUFAAWZWNI-UHFFFAOYSA-N
Related Categories
General description
N,N,N′,N′-Tetramethyl-p-phenylenediamine (TMPDA) is a redox reagent with low ionization potential widely used as an electron donor for photosystem I. It also acts as an electron acceptor in photosystem II.
Application
N,N,N′,N′-Tetramethyl-p-phenylenediamine (TMPDA) can be used:
- In the flow injection analysis of benzoyl peroxide.
- To study photoinduced electron transfer to halogenated solvents.
Disclaimer
May darken in storage.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
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Flow injection analysis of benzoyl peroxide using N, N, N, N-tetramethyl-p-phenylenediamine (TMPDA) and surfactants
Pharr DY & Tomsyck JA
Analytical Letters, 42(5), 821-832 (2009)
Ultrafast photoinduced electron transfer from N, N, N′ , N′ -tetramethyl-p-phenylenediamine and N, N, N′ , N′ -tetramethylbenzidine to dichloromethane
Boilet L, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 163(3), 529-536 (2004)
Interaction of N, N, N′ ,N′ -tetramethyl-p-phenylenediamine with photosystem II as revealed by thermoluminescence: reduction of the higher oxidation states of the Mn cluster and displacement of plastoquinone from the QB niche
Gauthier A, et al.
Biochimica et Biophysica Acta, 1757(11), 1547-1556 (2006)
Youngno Kim et al.
Scientific reports, 10(1), 16488-16488 (2020-10-07)
Stretchable materials are essential for next generation wearable and stretchable electronic devices. Intrinsically stretchable and highly conductive polymers (termed ISHCP) are designed with semi interpenetrating polymer networks (semi-IPN) that enable polymers to be simultaneously applied to transparent electrodes and electrochromic
P P Bawol et al.
Physical chemistry chemical physics : PCCP, 20(33), 21447-21456 (2018-08-09)
The reversibility of current Li-O2 batteries suffers from high charging overpotentials. To address this problem, the use of redox mediators has been proposed, which are supposed to improve the sluggish reaction kinetics of the oxygen evolution reaction via a solution
Global Trade Item Number
| SKU | GTIN |
|---|---|
| T7394-5G | 04061837372797 |
| T7394-25G | 04061837372780 |
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