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Merck
CN

T81906

Triphenylarsine

97%

Synonym(s):

Arsinetriphenyl

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About This Item

Linear Formula:
(C6H5)3As
CAS Number:
Molecular Weight:
306.23
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
210-032-9
MDL number:
Technical Service
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Quality Level

assay

97%

form

solid

reaction suitability

reagent type: catalyst

mp

58-61 °C (lit.)

SMILES string

c1ccc(cc1)[As](c2ccccc2)c3ccccc3

InChI

1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

BPLUKJNHPBNVQL-UHFFFAOYSA-N

General description

Triphenylarsine is an organoarsenic compound mainly used as a ligand and reagent in organic synthesis. It can also be used as a vapor deposition precursor to prepare nanomaterials.

Application

Triphenylarsine can be used:
  • As a CVD precursor to prepare As-doped carbon nanotubes with enhanced activity and long-term durability for the oxygen reduction reaction.
  • As an arsenic source to synthesize InAs nanocrystals.
  • As a ligand to accelerate the reaction rate of the Stille coupling reaction.
  • To prepare trichromophoric sensitizer for dye-sensitized solar cells.


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pictograms

Skull and crossbonesEnvironment

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3



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Tertiary arsine ligands for the Stille coupling reaction
Akane Chishiro, et al.
Dalton Transactions, 51, 95-103 (2022)
Novel As-doped, As and N-codoped carbon nanotubes as highly active and durable electrocatalysts for O2 reduction in alkaline medium
Ziwu Liu, et al.
Journal of Power Sources, 306, 535-540 (2016)
Benzene-thermal route to InP and InAs nanocrystals using triphenylphosphine and triphenylarsine as pnicogen sources
Junli Wang and Qing Yang
Chemistry Letters (Jpn), 37, 306-307 (2008)



Global Trade Item Number

SKUGTIN
T81906-100G04061837378966
T81906-25G04061837378973
T81906-5G04061837378980