产品名称
三苯基胂, 97%
InChI key
BPLUKJNHPBNVQL-UHFFFAOYSA-N
InChI
1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
SMILES string
c1ccc(cc1)[As](c2ccccc2)c3ccccc3
assay
97%
form
solid
reaction suitability
reagent type: catalyst
mp
58-61 °C (lit.)
Quality Level
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Application
三苯胂可用于：
- 作为CVD前体制备砷掺杂碳 纳米管，对氧还原反应的活性更强，具有长期稳定性。
- 作为砷源合成InAs 纳米晶体。
- 作为配体，促进 Stille偶联反应速率。
- 制备染料敏化太阳能电池的三色敏化剂(trichromophoric sensitizer)。
General description
三苯胂是一种有机砷化合物，在有机合成中主要用作配体和反应剂。也可作为气相沉积前体制备纳米材料。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
Benzene-thermal route to InP and InAs nanocrystals using triphenylphosphine and triphenylarsine as pnicogen sources
Junli Wang and Qing Yang
Chemistry Letters (Jpn), 37, 306-307 (2008)
Panchromatic Trichromophoric Sensitizer for Dye-Sensitized Solar Cells Using Antenna Effect
Julien Warnan, et al
Organic Letters, 13, 3944-3947 (2011)
Tertiary arsine ligands for the Stille coupling reaction
Akane Chishiro, et al.
Dalton Transactions, 51, 95-103 (2022)
Novel As-doped, As and N-codoped carbon nanotubes as highly active and durable electrocatalysts for O2 reduction in alkaline medium
Ziwu Liu, et al.
Journal of Power Sources, 306, 535-540 (2016)
Ryoto Inaba et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(59), 13400-13407 (2020-07-15)
Efficient catalytic arsa-Wittig reactions have been developed by using 1-phenylarsolane as a catalyst. A wide array of aldehydes was converted to the corresponding olefins in high yields with moderate to excellent E stereoselectivity in the presence of a catalytic amount
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