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Merck
CN

05-0015

Cacodylic acid

SAJ first grade

Synonym(s):

Dimethylarsinic acid, Dimethylarsonic acid, Hydroxydimethylarsine oxide

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About This Item

Linear Formula:
(CH3)2As(O)OH
CAS Number:
75-60-5
Molecular Weight:
138.00
EC Number:
200-883-4
UNSPSC Code:
12352106
PubChem Substance ID:
329748000
Beilstein/REAXYS Number:
1736965
MDL number:
MFCD00002095

Key Documents

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grade

SAJ first grade

form

solid

reaction suitability

reagent type: catalyst
core: arsenic

availability

available only in Japan

SMILES string

C[As](C)(O)=O

InChI

1S/C2H7AsO2/c1-3(2,4)5/h1-2H3,(H,4,5)

InChI key

OGGXGZAMXPVRFZ-UHFFFAOYSA-N

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
A1379

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Hua Naranmandura et al.
Analytical and bioanalytical chemistry, 405(6), 1885-1891 (2012-06-27)
Arsenic (+3 oxidation state) methyltransferase (As3mt) plays a central role in the enzymatically catalyzed conversion of inorganic arsenic into methylated metabolites. Most studies of the metabolism and disposition of arsenicals following exposure to inorganic arsenic focus on the formation and
Tomohiro Narukawa et al.
Journal of agricultural and food chemistry, 60(4), 1122-1127 (2012-01-10)
A monitoring test for arsenic species in white rice flour was developed and applied to flours made from 20 samples of polished rice collected from locations all over Japan. The arsenic species in white rice flour made from five samples
Kavitha Marapakala et al.
Biochemistry, 51(5), 944-951 (2012-01-20)
The enzyme As(III) S-adenosylmethionine methyltransferase (EC 2.1.1.137) (ArsM or AS3MT) is found in members of every kingdom, from bacteria to humans. In these enzymes, there are three conserved cysteine residues at positions 72, 174, and 224 in the CmArsM orthologue
Hua Naranmandura et al.
Toxicology and applied pharmacology, 260(3), 241-249 (2012-03-20)
The purpose of present study was to characterize the endoplasmic reticulum stress and generation of ROS in rat liver RLC-16 cells by exposing to trivalent dimethylarsinous acid (DMAIII) and compared with that of trivalent arsenite (iAsIII) and monomethylarsonous acid (MMAIII).
Hua Naranmandura et al.
Toxicological sciences : an official journal of the Society of Toxicology, 128(1), 137-146 (2012-04-28)
Arsenic is known to be a human carcinogen as well as one of the most effective drugs for treatment of patients with acute promyelocytic leukemia. The intermediate metabolites of arsenic, monomethylarsonous acid (MMA(III)) and dimethylarsinous acid (DMA(III)), are formed by
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