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Merck
CN

386464

Diisopropylamine

99.95%, liquid, purified by redistillation

Synonym(s):

DIPA

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About This Item

Linear Formula:
(CH3)2CHNHCH(CH3)2
CAS Number:
Molecular Weight:
101.19
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-558-5
MDL number:
Beilstein/REAXYS Number:
605284
Assay:
99.95%
Bp:
84 °C (lit.)
Vapor pressure:
50 mmHg ( 20 °C)
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Product Name

Diisopropylamine, purified by redistillation, 99.95%

vapor density

3.5 (vs air)

Quality Level

vapor pressure

50 mmHg ( 20 °C)

assay

99.95%

form

liquid

autoignition temp.

599 °F

purified by

redistillation

expl. lim.

8.5 %

refractive index

n20/D 1.392 (lit.)

bp

84 °C (lit.)

mp

−61 °C (lit.)

solubility

water: soluble 110 g/L at 25 °C

density

0.722 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CC(C)NC(C)C

InChI

1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3

InChI key

UAOMVDZJSHZZME-UHFFFAOYSA-N

General description

Diisopropylamine (DIPA) is an aliphatic secondary amine widely used as an organic base in organic synthesis. Its standard molar enthalpy of formation and combustion has been measured.

Application

Diisopropylamine may be used in the following processes:
  • Synthesis of diisopropylamine methyl urea (DMU).
  • Synthesis of N,N-diisopropyl quinoline-2-carboxamide.
  • Synthesis of 3-N-sulfonylamidine coumarins.
  • Synthesis of N-chloroamine, an intermediate to generate amides.


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signalword

Danger

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

flash_point_f

7.8 °F - closed cup

flash_point_c

-13.45 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - PMT - Repr. 1B - Skin Corr. 1B - STOT SE 3 - vPvM

Regulatory Information

危险化学品

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Enthalpies of combustion of di-n-propylamine, diisopropylamine, diisobutylamine, and di-sec-butylamine.
Ribeiro da Silva MAV, et al.
The Journal of Chemical Thermodynamics, 29(9), 1025-1030 (1997)
A simple and novel amide ligand based on quinoline derivative used for palladium-catalyzed Suzuki coupling reaction.
Liu H, et al.
Journal of Organometallic Chemistry, 794, 27-32 (2015)
Microwave-Assisted Copper-Catalyzed Four Component Tandem Synthesis of 3-N-Sulfonylamidine Coumarins.
Murugavel G and Punniyamurthy T.
The Journal of Organic Chemistry, 80 (12), 6291-6299 (2015)



Global Trade Item Number

SKUGTIN
386464-100ML04061831966930
386464-1L04061838127006
386464-4X100ML04061838127013