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471283

Triethylamine

Name: Triethylamine
Brand: SIAL

≥99.5%, liquid

Synonym(s):

N,N-Diethylethanamine

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About This Item

Linear Formula:

(C₂H₅)₃N

CAS Number:

121-44-8

Molecular Weight:

101.19

NACRES:

NA.21

PubChem Substance ID:

24870713

UNSPSC Code:

12352116

EC Number:

204-469-4

MDL number:

MFCD00009051

Beilstein/REAXYS Number:

605283

Assay:

≥99.5%

Bp:

88.8 °C (lit.)

Vapor pressure:

51.75 mmHg ( 20 °C)

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Product Name

Triethylamine, ≥99.5%

vapor density

3.5 (vs air)

Quality Level

100

vapor pressure

51.75 mmHg ( 20 °C)

assay

≥99.5%

form

liquid

autoignition temp.

593 °F

expl. lim.

8 %

impurities

≤0.1% (Karl Fischer)

refractive index

n20/D 1.401 (lit.)

pH

12.7 (15 °C, 100 g/L)

bp

88.8 °C (lit.)

mp

−115 °C (lit.)

solubility

water: soluble 112 g/L at 20 °C

density

0.726 g/mL at 25 °C (lit.)

functional group

amine

storage temp.

room temp

SMILES string

CCN(CC)CC

InChI

1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

ZMANZCXQSJIPKH-UHFFFAOYSA-N

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General description

Triethylamine (TEA, Et₃N) is an aliphatic amine. Its addition to matrix-assisted laser desorption/ionization (MALDI) matrices affords transparent liquid matrices with enhanced ability for spatial resolution during MALDI mass spectrometric (MS) imaging. A head-space gas chromatography (GC) procedure for the determination of triethylamine in active pharmaceutical ingredients has been reported. The viscosity coefficient of triethylamine vapor over a range of density and temperature has been measured.

Application

Triethylamine has been used during the synthesis of:

5′-dimethoxytrityl-5-(fur-2-yl)-2′-deoxyuridine
3′-(2-cyanoethyl)diisopropylphosphoramidite-5′-dimethoxytrityl-5-(fur-2-yl)-2′-deoxyuridine
polyethylenimine600-β-cyclodextrin (PEI₆₀₀-β-CyD)

It may be used as a homogeneous catalyst for the preparation of glycerol dicarbonate, via transesterification reaction between glycerol and dimethyl carbonate (DMC).

Packaging

18 L packaged in closed-head steel drums; 100 mL, 500 mL, 2 L, 6×500 mL, 4 L packaged in glass bottles; 200 L packaged in Kilo-Lab^® steel cylinders

Legal Information

Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS02,GHS06,GHS05

signalword

Danger

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

flash_point_f

12.2 °F - closed cup

flash_point_c

-11 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

hcodes

H225,H301 + H311 + H331,H314,H335

pcodes

P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Regulatory Information

危险化学品

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Synthesis of glycerol 1,2-carbonate by transesterification of glycerol with dimethyl carbonate using triethylamine as a facile separable homogeneous catalyst.

Ochoa-Gomez JR, et al.

Green Chemistry, 14(12), 3368-3376 (2012)

GC quantification of cyclopropylamine, diethylamine and triethylamine in active pharmaceutical ingredients.

Raghuram P, et al.

Chromatographia, 71(9-10), 963-966 (2010)

Transparent triethylamine-containing MALDI matrices.

Rubakhin SS and Sweedler JV.

Israel J. Chem., 47(2), 185-193 (2007)

Synthesis and site-specific incorporation of a simple fluorescent pyrimidine.

Nicholas J Greco et al.

Nature protocols, 2(2), 305-316 (2007-04-05)

We describe procedures for the synthesis of a fluorescent pyrimidine analog and its site-specific incorporation into a DNA oligomer. The 5'-protected and 3'-activated nucleoside 4 is synthesized in three steps with an overall yield of 40%. Site-specific incorporation into a

The viscosity of triethylamine vapor at low densities and in the saturated vapor phase.

Teske V, et al.

Fluid Phase Equilibria, 293(2), 190-195 (2010)

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Global Trade Item Number

SKU	GTIN
471283-2.5L	04061837548840
471283-100ML	04061837548833
471283-4L	04061832359731
471283-4X100ML	04061832359748
471283-18L	04061832359717
471283-6X500ML	04061837548895
471283-4X4L	04061832359755
471283-200L	04061838161710
471283-2L	04061832359724
471283-500ML	04061837548871

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