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Merck
CN

64270

Methanesulfonyl chloride

purum, ≥98.0% (AT)

Synonym(s):

Methyl sulfonyl chloride, Mesyl chloride

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About This Item

Linear Formula:
CH3SO2Cl
CAS Number:
Molecular Weight:
114.55
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-706-1
Beilstein/REAXYS Number:
506297
MDL number:
Assay:
≥98.0% (AT)
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grade

purum

Quality Level

assay

≥98.0% (AT)

refractive index

n20/D 1.452

bp

60 °C/21 mmHg (lit.)

density

1.48 g/mL at 25 °C (lit.)

SMILES string

CS(Cl)(=O)=O

InChI

1S/CH3ClO2S/c1-5(2,3)4/h1H3

InChI key

QARBMVPHQWIHKH-UHFFFAOYSA-N

Application

Methanesulfonyl chloride can be used for the mesylation of primary alcohols to synthesize the corresponding methanesulfonates. It may also be used for the conversion of amines to the corresponding sulfonamides.


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pictograms

Skull and crossbonesCorrosion

signalword

Danger

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

215.6 °F - closed cup

flash_point_c

102 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

Regulatory Information

监管及禁止进口产品

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Methanesulfonyl Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2007)
Methanesulfonyl Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Base-free monosulfonylation of amines using tosyl or mesyl chloride in water
Kamal A
Tetrahedron Letters, 49(2), 348-353 (2008)



Global Trade Item Number

SKUGTIN
T134000004061833801154
T8441-1KG04061837379253
T8441-100G04061837379239
T8625-10G04061837379406
T8625-100G04061837379390
T8441-10G04061833352366
89179-10G04061833075593
816012002504022536423654
61506-100MG04061832700182
61506-1G04061834232940
T8441-25G04061835550326
T8625-25G04061837379437
89179-50G04061833075609
108411010004022536104140
108411001004022536104133
108411100004022536104157
108411901004022536692845
816012010004022536423661