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Merck
CN

915742

Grubbs Catalyst® M208

Umicore, powder

Synonym(s):

CatMETium RF3, Tricyclohexylphosphine[4,5-dimethyl-1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene][2- thienylmethylene]ruthenium(II) dichloride, [(Me)2-IMes]Ru(PCy3)(2-thienylmethylene)Cl2

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About This Item

Empirical Formula (Hill Notation):
C46H65Cl2N2PRuS
CAS Number:
1190427-50-9
Molecular Weight:
881.04
MDL number:
MFCD16038135
UNSPSC Code:
12352103
NACRES:
NA.22

Key Documents

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Product Name

Grubbs Catalyst® M208, Umicore

SMILES string

[Ru](=C5N(C(=C(N5c7c(cc(cc7C)C)C)C)C)c6c(cc(cc6C)C)C)(=Cc4[s]ccc4)(Cl)Cl.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1

InChI

1S/C23H28N2.C18H33P.C5H4S.2ClH.Ru/c1-14-9-16(3)22(17(4)10-14)24-13-25(21(8)20(24)7)23-18(5)11-15(2)12-19(23)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-5-3-2-4-6-5;;;/h9-12H,1-8H3;16-18H,1-15H2;1-4H;2*1H;/q;;;;;+2/p-2

InChI key

NMUNQTSQYLEOMN-UHFFFAOYSA-L

Quality Level

100

product line

Grubbs Catalyst® M200 Series

form

powder

manufacturer/tradename

Grubbs Catalyst® M200 Series

mp

>300 °C

Related Categories

Application

Umicore Grubbs Catalyst M208 is a homogeneous catalyst useful for alkene metathesis, especially for cross-metathesis, ring-closing metathesis and self-metathesis.

Learn more about our metathesis catalysts

Preparation Note

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Legal Information

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Self-heat. 1 - Skin Sens. 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP6710

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