92337
Bromotrimethylsilane
purum, ≥97.0% (AT)
Synonym(s):
TMBS, Trimethylbromosilane, Trimethylsilyl bromide
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About This Item
Linear Formula:
(CH3)3SiBr
CAS Number:
Molecular Weight:
153.09
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-672-0
Beilstein/REAXYS Number:
1731135
MDL number:
Assay:
≥97.0% (AT)
Form:
liquid
grade
purum
Quality Segment
assay
≥97.0% (AT)
form
liquid
contains
silver wool as stabilizer
refractive index
n20/D 1.424
bp
79 °C (lit.)
density
1.16 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)Br
InChI
1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
InChI key
IYYIVELXUANFED-UHFFFAOYSA-N
General description
Bromotrimethylsilane is used with Cl3 to catalyze the direct allylation of a variety of alcohols with allyltrimethylsilane.
Application
Bromotrimethylsilane may be used as a derivatizing reagent for the determination of alkyl lysophospholipids in cell culture media using gas chromatography technique.
Other Notes
Powerful silylating agent ; Cleavage of ethers ; Smooth cleavage of phosphonic and phosphoric alkyl esters
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signalword
Danger
target_organs
Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
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