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Merck
CN

93000

Trityl chloride

purum, ≥97.0% (HPLC), ≥97.0% (AT)

Synonym(s):

Chlorotriphenylmethane, Triphenylchloromethane, Triphenylmethyl chloride

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About This Item

Linear Formula:
(C6H5)3CCl
CAS Number:
76-83-5
Molecular Weight:
278.78
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
329770191
EC Number:
200-986-4
Beilstein/REAXYS Number:
397363
MDL number:
MFCD00000813

Key Documents

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Product Name

Trityl chloride, purum, ≥97.0% (HPLC), ≥97.0% (AT)

InChI key

JBWKIWSBJXDJDT-UHFFFAOYSA-N

InChI

1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

SMILES string

ClC(c1ccccc1)(c2ccccc2)c3ccccc3

grade

purum

assay

≥97.0% (AT)
≥97.0% (HPLC)

form

powder

ign. residue

≤0.2% (as SO4)

bp

230-235 °C/20 mmHg (lit.)

mp

109-112 °C (lit.)
109-113 °C

solubility

chloroform: 0.1 g/mL, clear

functional group

chloro
phenyl

Quality Level

200

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Application

  • Organic Synthesis: Research on the synthesis of 1, 2, 4-triazine derivatives, exploring the condensation reactions of trityl chloride with various compounds (Majid et al., 2020).

Other Notes

Reagent for tritylations;; Efficient method of tritylation of sensitive compounds and their subsequent detritylation

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF3742V
WXBF2663V
BCCK8945
WXBF2119V
BCCK3781

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J S Davidson et al.
Biochimica et biophysica acta, 847(1), 1-7 (1985-10-30)
Intercellular junctional communication was measured using [14C]citrulline incorporation in co-cultures of argininosuccinate synthetase-deficient and argininosuccinate lyase-deficient human fibroblasts. Triphenylmethane, triphenylmethylchloride and tetraphenylboron inhibited communication at concentrations at least 12-fold lower than cytotoxic concentrations. This inhibition was of rapid onset and
Vijayavitthal T Mathad et al.
Natural product research, 20(12), 1053-1058 (2006-11-28)
Jones oxidation of Andrographolide (1), gave mixture of three products (3-dehydroandrographolide (5), 3,19-bis dehydroandrographolide (6) and 19-dehydroandrographolide (7). Tritylation of andrographolide at C19-OH resulted to products 8 and diene 9, which can be converted to its acetate 10 and oxidation
Ryuichi Hasegawa et al.
Congenital anomalies, 45(4), 137-145 (2005-12-20)
To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 days starting at 5-6 weeks of age respectively, under
R Hasegawa et al.
Regulatory toxicology and pharmacology : RTP, 47(3), 296-307 (2006-12-13)
We comprehensively re-analyzed the toxicity data for 18 industrial chemicals from repeated oral exposures in newborn and young rats, which were previously published. Two new toxicity endpoints specific to this comparative analysis were identified, the first, the presumed no observed
V. Kohli et al.
Tetrahedron Letters, 21, 2683-2683 (1980)
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