Merck
CN
Search Within

377996

Applied Filters:
Keyword:'377996'
Showing 31-60 of 70 results for "377996" within Papers
Zhishan Su et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(5), 1637-1646 (2012-12-15)
The mechanism and the origin of selectivity of the asymmetric Strecker reaction catalyzed by a Ti(IV)-complex catalyst generated from a cinchona alkaloid, achiral substituted 2,2'-biphenol, and tetraisopropyl titanate have been investigated by DFT and ONIOM methods. The calculations indicate that
Jae-Yup Kim et al.
ACS nano, 9(11), 11286-11295 (2015-10-03)
Copper-indium-selenide (CISe) quantum dots (QDs) are a promising alternative to the toxic cadmium- and lead-chalcogenide QDs generally used in photovoltaics due to their low toxicity, narrow band gap, and high absorption coefficient. Here, we demonstrate that the photovoltaic performance of
Yi-Chun Hsu et al.
Chemical & pharmaceutical bulletin, 53(10), 1266-1269 (2005-10-06)
The direct activation of C-O bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium(IV) isoproxide and 4 A molecular sieves. The acidic and less nucleophilic anilines such as diphenylamine
Josephine Selvaraj et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(10), 2010-2018 (2014-07-01)
Nitrogen (N)-doped reduced graphene oxide (nRGO) is systematically incorporated into a TiO(2) -CdS photoelectrochemical (PEC) cell and its role is examined in the three main components of the cell: 1) the CdS-sensitized TiO(2) photoanode, 2) the cathode, and 3) the
Jun Lu et al.
Nature communications, 5, 5693-5693 (2014-12-17)
The capacity fade of lithium manganate-based cells is associated with the dissolution of Mn from cathode/electrolyte interface due to the disproportionation reaction of Mn(III), and the subsequent deposition of Mn(II) on the anode. Suppressing the dissolution of Mn from the
Henrique Antonio Mendonça Faria et al.
Materials science & engineering. C, Materials for biological applications, 56, 260-268 (2015-08-08)
The structural and electronic properties of titanium oxide nanotubes (TiO2) have attracted considerable attention for the development of therapeutic devices and imaging probes for nanomedicine. However, the fluorescence response of TiO2 has typically been within ultraviolet spectrum. In this study
Chiara Ingrosso et al.
ACS applied materials & interfaces, 7(28), 15494-15505 (2015-07-08)
A novel UV-light-curable nanocomposite material formed of a methacrylic-siloxane resin loaded with 1 wt % oleic acid and 3-(trimethoxysilyl)propyl methacrylate silane (OLEA/MEMO)-coated TiO2 nanorods (NRs) has been manufactured as a potential self-curing structural coating material for protection of monuments and
Amir Behzadnia et al.
Ultrasonics sonochemistry, 27, 10-21 (2015-07-19)
In this study, N-doped ZnO/TiO2 core-shell nanocomposite was successfully sonosynthesized and sonofabricated on wool fabric through a facile one-step method under ambient pressure and low temperature (75-80°C) as a novel photo-catalyst nanocomposite on textile material. The differences between crystalline phase
Tze-Bin Song et al.
ACS applied materials & interfaces, 7(44), 24601-24607 (2015-10-22)
Solution-processed silver nanowire networks are one of the promising candidates to replace a traditional indium tin oxide as next-generation transparent and flexible electrodes due to their ease of processing, moderate flexibility, high transparency, and low sheet resistance. To date, however
Fengxiang Chen et al.
ACS nano, 11(10), 10330-10336 (2017-09-22)
Carbon fiber is a good candidate in various applications, including in the military, structural, sports equipment, energy storage, and infrastructure. Coloring of carbon fiber has been a big challenge for decades due to their high degrees of crystallization and insufficient
Guangqing Guo et al.
The journal of physical chemistry. B, 109(40), 18781-18785 (2006-07-21)
Nanoscaled TiO2 powders with narrow size dispersion were prepared in supercritical carbon dioxide via non-hydrolytic acylation/deacylation of titanium alkoxide precursors with or without tris-fluorination. The microstructures of these powders were characterized by spectroscopic (FTIR, TGA, and XRD), microscopic (SEM or
Laxman Gouda et al.
The journal of physical chemistry letters, 6(22), 4640-4645 (2015-12-02)
The high open-circuit potential (Voc) achieved by perovskite solar cells (PSCs) is one of the keys to their success. The Voc analysis is essential to understand their working mechanisms. A large number of CH3NH3PbI3-xClx PSCs were fabricated on single large-area
Matthew T McDowell et al.
ACS applied materials & interfaces, 7(28), 15189-15199 (2015-06-18)
Light absorbers with moderate band gaps (1-2 eV) are required for high-efficiency solar fuels devices, but most semiconducting photoanodes undergo photocorrosion or passivation in aqueous solution. Amorphous TiO2 deposited by atomic-layer deposition (ALD) onto various n-type semiconductors (Si, GaAs, GaP
Sreenivasan Koliyat Parayil et al.
Journal of nanoscience and nanotechnology, 15(9), 7285-7292 (2015-12-31)
TiO2-SiO2 mixed oxide photocatalyst materials responsive to simulated solar light illumination have been synthesized by sol-gel method in various polar and nonpolar organic solvent mixtures. The photocatalysts were characterized by numerous experimental techniques and investigated for the photocatalytic conversion of
Bridget K Mutuma et al.
Journal of colloid and interface science, 442, 1-7 (2014-12-17)
TiO2 photocatalysts with a mixture of different TiO2 crystal polymorphs have customarily been synthesized hydrothermally at high temperatures using complicated and expensive equipment. In this study TiO2 nanoparticles with a mixture of TiO2 crystals were synthesized using a modified sol-gel
Long Yang et al.
Analytica chimica acta, 852, 28-36 (2014-12-03)
A titanium dioxide-silicon carbide nanohybrid (TiO2-SiC) with enhanced electrochemical performance was successfully prepared through a facile generic in situ growth strategy. Monodispersed ultrafine palladium nanoparticles (Pd NPs) with a uniform size of ∼2.3 nm were successfully obtained on the TiO2-SiC
Elena Soriano et al.
Carbohydrate research, 343(10-11), 1835-1839 (2008-04-02)
The chelation of the Lewis acid Ti(OiPr)(4) provides the necessary conformational control to induce pi-facial selectivity on the cyanation process. The steric hindrance imposed by the alpha-substituent restrains the addition for l-amino acid derivatives.
Rafael Leite de Oliveira et al.
Journal of hazardous materials, 205-206, 1-9 (2012-01-11)
The present work describes a more efficient methodology for the chlorination of water containing disperse dyes, where the chlorinated byproducts identified by mass spectra are compared. For this investigation, we tested the degradation of CI Disperse Blue 291 dye, 2-[(2-Bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)-4-methoxyacetanilide)
E Silva Junior et al.
Dalton transactions (Cambridge, England : 2003), 44(7), 3159-3175 (2015-01-13)
The focus of this paper is on the analysis of the structural and electronic order-disorder effects at long, medium and short ranges of titanium dioxide (TiO2) nanoparticles synthesized by the sol-gel process followed by the microwave-assisted solvothermal (MAS) method at
Raju C Asha et al.
Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 50(10), 1011-1019 (2015-06-30)
The presence of sulfamethoxazole (SMX) in a real-time poultry wastewater was identified via HPLC analysis. Subsequently, SMX removal from the poultry wastewater was investigated using a continuous-mode membrane-photocatalytic slurry reactor (MPSR). The real-time poultry wastewater was found to have an
Chong-Dao Lu et al.
Chemical communications (Cambridge, England), (20)(20), 2624-2626 (2005-05-19)
The rhodium(II)-catalyzed three-component reaction of diazoacetates, titanium alkoxides and aldehydes is shown to give alpha-alkoxyl-beta-hydroxyl acid derivatives; the novel C-C bond formation reaction is proposed to occur through oxonium ylides derived from diazo compounds and titanium alkoxides, and followed by
Choumini Balasanthiran et al.
Journal of colloid and interface science, 459, 63-69 (2015-08-12)
The surface of oleic acid stabilized rod-shape anatase TiO2 nanocrystals was modified by adsorption of Eu(3+) ions. The Eu(3+) attachment showed Langmuir adsorption behavior, thus the loading of Eu(3+) could be controlled precisely up to surface saturation coverage. The Eu(3+)-TiO2
Laszlo Sipos et al.
Biomacromolecules, 6(5), 2570-2582 (2005-09-13)
A poly(styrene-b-isobutylene-b-styrene) (SIBS) triblock polymer is employed as the polymer drug carrier for the TAXUS Express2 Paclitaxel-Eluting Coronary Stent system (Boston Scientific Corp.). It has been shown that the release of paclitaxel (PTx) from SIBS can be modulated by modification
Dong Hoe Kim et al.
ChemSusChem, 8(14), 2392-2398 (2015-04-22)
Perovskite solar cells (PSCs) are the most promising candidates as next-generation solar energy conversion systems. To design a highly efficient PSC, understanding electronic properties of mesoporous metal oxides is essential. Herein, we explore the effect of Nb doping of TiO2
Alfred J Wooten et al.
Organic letters, 9(3), 381-384 (2007-01-26)
[reaction: see text] We report the catalytic asymmetric allylation of ketones under highly concentrated reaction conditions with a catalyst generated from titanium tetraisopropoxide and BINOL (1:2 ratio) in the presence of isopropanol. This catalyst promotes the addition of tetraallylstannane to
Zarrin Es'haghi et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 980, 55-64 (2015-01-16)
A new design of hollow fiber solid-liquid phase microextraction (HF-SLPME) was developed for the determination of benzodiazepines (BZPs) in hair, urine and wastewater. The membrane extraction with 1-pentyl-3-methylimidazolium bromide coated titanium dioxide ([PMIM]Br@TiO2) sorbent used in this research is a
R Said et al.
Journal of nanoscience and nanotechnology, 10(4), 2552-2557 (2010-04-02)
RF-PECVD was used to prepare amorphous of carbon (DLC) onto stainless steel 316 and glass substrates. The substrates were negatively biased at between 100 V to 400 V. Thin films of DLC have been deposited using C2H2 and titanium isopropoxide
Mitsunobu Iwasaki et al.
Journal of colloid and interface science, 326(2), 537-540 (2008-08-16)
Nanometer-sized TiO(2) island structure on the platy hydroxyapatite nanocrystals (HAp) has been accomplished by two-step emulsion process. At the first step, platy HAp nanocrystals, of which size was in the range of 70-200 nm after heat-treatment at 1078 K for
Chang-Min Yoon et al.
ACS applied materials & interfaces, 7(34), 18977-18984 (2015-08-13)
A series of alkaline earth metal-doped hollow SiO2/TiO2 spheres (EM-HST) are prepared as electrorheological (ER) materials via sonication-mediated etching method with various alkaline earth metal hydroxides as the etchant. The EM-HST spheres are assessed to determine how their hollow interior
Murat Ozmen et al.
Aquatic toxicology (Amsterdam, Netherlands), 165, 144-153 (2015-06-04)
The toxic effects of two selected xenobiotics, bisphenol A (BPA) and atrazine (ATZ), were evaluated after photocatalytic degradation using nano-sized, Mn-doped TiO2. Undoped and Mn-doped TiO2 nanoparticles were synthesized. The samples were characterized by X-ray diffractometry (XRD), scanning electron microscopy
Page 2 of 3