, 43–98%
dr = 96:4 to 99:1
84–97% ee
PivCl (1.5 equiv)
i-Pr2NEt (4.0 equiv)
CH2Cl2, –30 oC
16 or 40 h
31c (10 mol %)
21 examples, 62–87%
dr = 80:20 to 98:2
83–99% ee
Ar2
Ar1
P CH3
• HI
671584
cataCXium® AHI 714951-87-8 486.45 X X • Arylation
N
Ph
P
t-Bu
t-Bu
672661
cataCXium® PtB 672937-61-0 287.38 X X • Dehydrogenation of iso-propanol
N
Ph