- Induction in urothermal synthesis of chiral porous materials from achiral precursors.
Induction in urothermal synthesis of chiral porous materials from achiral precursors.
Chemical communications (Cambridge, England) (2011-03-29)
Yao Kang, Shumei Chen, Fei Wang, Jian Zhang, Xianhui Bu
PMID21442101
ABSTRACT
Special asymmetric crystallization of porous framework materials from achiral precursors under urothermal conditions is successfully achieved by using an enantiopure liquid as a co-solvent and chirality induction agent, which provides a new strategy for the synthesis of homochiral porous materials containing only achiral building blocks.
MATERIALS
Product Number
Brand
Product Description
Supelco
(+)-Carvone, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland