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  • Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.

Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.

Organic letters (2012-03-28)
Kun Shen, Xiuling Han, Xiyan Lu
ABSTRACT

Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
4-Chlorophenylboronic acid, 95%
Sigma-Aldrich
4-Bromophenylboronic acid, ≥95.0%