Merck
CN

Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.

Chemical communications (Cambridge, England) (2011-12-20)
Ben W Glasspoole, Kazem Ghozati, Jonathon W Moir, Cathleen M Crudden
ABSTRACT

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Methylboronic acid, 97%