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  • Conductivity and FTIR studies on PEO-LiX [X: CF3SO3(-), SO4(2-)] polymer electrolytes.

Conductivity and FTIR studies on PEO-LiX [X: CF3SO3(-), SO4(2-)] polymer electrolytes.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (2007-06-30)
S Ramesh, Tai Fung Yuen, Chia Jun Shen
ABSTRACT

Polymer electrolytes based on poly(ethylene oxide)-lithium triflate (PEO-LiCF3SO3) and poly(ethylene oxide)-lithium sulphate (PEO-Li2S4) were prepared by using solution casting method. Measurements of conductivity and dielectric were carried out on these films as a function of frequency at various temperatures. It was observed that PEO-LiCF3SO3 polymer electrolytes have higher conductivity. The interaction between PEO and Li salts were studied by Fourier transform infrared (FTIR).

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Lithium sulfate, purum p.a., ≥98.0% (T)
Sigma-Aldrich
Lithium sulfate, ≥99.99% trace metals basis
Sigma-Aldrich
Lithium sulfate, ≥98.5% (titration)