- Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal.
Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal.
Chemical communications (Cambridge, England) (2011-06-11)
Yuh Hijikata, Satoshi Horike, Daisuke Tanaka, Juergen Groll, Motohiro Mizuno, Jungeun Kim, Masaki Takata, Susumu Kitagawa
PMID21660332
ABSTRACT
We have demonstrated downsizing effects of the soft porous crystal, [Zn(isophthalate)(4,4'-bipyridyl)](n) (CID-1), on the adsorption behavior between CID-1 and CID-1 nanocrystal (NCID-1). The difference results from the packing crystal structures and the dynamics of the frameworks.