- Catalytic C-H bond activation at nanoscale Lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons.
Catalytic C-H bond activation at nanoscale Lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons.
Chemistry (Weinheim an der Bergstrasse, Germany) (2011-11-30)
Martin H G Prechtl, Michael Teltewskoi, Anton Dimitrov, Erhard Kemnitz, Thomas Braun
PMID22125129
ABSTRACT
Nanoscopic amorphous Lewis acidic aluminium fluorides, such as aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF(3)), are capable of activating C-H bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).
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