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  • Synthesis of furo[3,2-b]pyrrole-5-carboxhydrazides and their Cu, Co and Ni complexes.

Synthesis of furo[3,2-b]pyrrole-5-carboxhydrazides and their Cu, Co and Ni complexes.

TheScientificWorldJournal (2012-05-18)
Renata Gašparová, Ján Titiš, Filip Kraic
ABSTRACT

Carboxhydrazides 3 were synthesized by reaction of substituted furo[3,2-b]pyrrole-5-carboxhydrazides 1 with 4-oxo-4H-chromene-2-carboxaldehyde 2 in the presence of 3-methyl-benzenesulfonic acid in ethanol. Carboxhydrazides 3 were used as ligands for synthesis of Cu, Co, and Ni complexes 4.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Sodium benzenesulfonate, 97%
Sigma-Aldrich
Benzenesulfonic acid, 98.0% (T)
Sigma-Aldrich
Benzenesulfonic acid, technical grade, 90%