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  • A coumarin-Meldrum's acid conjugate based chemodosimetric probe for cyanide.

A coumarin-Meldrum's acid conjugate based chemodosimetric probe for cyanide.

Chemical communications (Cambridge, England) (2012-10-26)
Hongda Li, Zhi Wen, Longyi Jin, Yuhe Kan, Bingzhu Yin
ABSTRACT

A highly reactive and selective chemodosimetric probe for cyanide was synthesized based on alkylidene Meldrum's acid as a novel cyanide reaction site. A theoretical study was conducted to rationalize the high reactivity and the photophysical properties of probe 1 and the 1-CN adduct.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
2,2-Dimethyl-1,3-dioxane-4,6-dione, 98%