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  • Bis-sulfonic acid ionic liquids for the conversion of fructose to 5-hydroxymethyl-2-furfural.

Bis-sulfonic acid ionic liquids for the conversion of fructose to 5-hydroxymethyl-2-furfural.

Molecules (Basel, Switzerland) (2012-11-02)
Sang Eun Sim, Sunjeong Kwon, Sangho Koo
ABSTRACT

Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
5-Hydroxymethyl-2-furaldehyde, 99%
Supelco
5-(Hydroxymethyl)furfural, analytical standard
Sigma-Aldrich
5-(Hydroxymethyl)furfural, ≥99%, FG