- Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation.
Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation.
Chemical communications (Cambridge, England) (2013-01-09)
Benito Alcaide, Pedro Almendros, Sara Cembellín, Teresa Martínez del Campo, Israel Fernández
PMID23295954
ABSTRACT
The divergent gold-catalysed reactivity (C(sp(2))-H versus C(sp(3))-H) of aryloxy-tethered allenes has been uncovered.